Silicon, a tetravalent metalloid and semiconductor with symbol Si and atomic number 14, is a critical element with various applications. Known for its blue-grey metallic luster, hardness, and brittle crystalline structure, it sits below carbon and above germanium, tin, lead, and flerovium in the periodic table. While relatively unreactive, it plays a crucial role in plant physiology and metabolism. Silicon's importance in electrical devices like transistors, solar cells, and integrated circuits stems from its unique properties, including a significant band gap, broad optical transmission and absorption spectra, surface roughening capabilities, and effectiveness as an anti-reflection coating.
Indian physicist Jagadish Chandra Bose developed a radio crystal detector using galena in 1901.
In 1906, American engineer Greenleaf Whittier Pickard achieved a breakthrough by developing the first silicon semiconductor device, a silicon radio crystal detector.
Russell Ohl made a groundbreaking discovery in 1940 - the p–n junction and photovoltaic effects in silicon, laying the foundation for silicon-based electronics.
The need for radar microwave detector crystals during World War II in 1941 drove significant advancements in the development of techniques for producing high-purity germanium and silicon crystals.
In 1947, physicist William Shockley developed the theoretical framework for a field-effect amplifier using germanium and silicon. While he couldn't create a working device with these materials, his work was crucial. That same year, John Bardeen and Walter Brattain, working under Shockley's guidance, built the first functioning transistor, a point-contact transistor.
Marking a pivotal moment in the advancement of electronics, physical chemist Morris Tanenbaum fabricated the first silicon junction transistor at Bell Labs in 1954.
In a serendipitous discovery in 1955, Carl Frosch and Lincoln Derick at Bell Labs found that silicon dioxide (SiO2) could be grown on silicon.
Building on their earlier discovery, Frosch and Derick proposed in 1958 that silicon dioxide could be used as a mask during diffusion processes in silicon fabrication.
A novel allotrope of silicon, known as silicene, was successfully synthesized in 2010, marking a significant advancement in silicon chemistry.
By 2013, it was projected that polycrystalline silicon production, primarily used in solar cells, would reach a substantial 200,000 metric tons per year. In contrast, monocrystalline semiconductor-grade silicon production was expected to be significantly lower.
In 2019, a significant 32.4% of the semiconductor market segment was dedicated to networks and communications devices.
The semiconductor industry is expected to experience substantial growth, with projections indicating it will reach $726.73 billion by 2027.